Publicaciones de Rogue Scholar

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Publicado in Henry Rzepa's Blog

The reduction of cinnamaldehyde by lithium aluminium hydride (LAH) was reported in a classic series of experiments[cite]10.1021/ja01197a060[/cite],[cite]10.1021/ja01202a082[/cite],[cite]10.1021/ja01190a082[/cite] dating from 1947-8. The reaction was first introduced into the organic chemistry laboratories here at Imperial College decades ago, vanished for a short period, and has recently been reintroduced again. The experiment is

Publicado in Henry Rzepa's Blog

The diazo-coupling reaction dates back to the 1850s (and a close association with Imperial College via the first professor of chemistry there, August von Hofmann) and its mechanism was much studied in the heyday of physical organic chemistry.[cite]10.1021/ja00830a009[/cite] Nick Greeves, purveyor of the excellent ChemTube3D site, contacted me about the transition state (I have commented previously on this aspect of aromatic

Publicado in Henry Rzepa's Blog

Henry Armstrong studied at the Royal College of Chemistry from 1865-7 and spent his subsequent career as an organic chemist at the Central College of the Imperial college of Science and technology until he retired in 1912.