Publié in Henry Rzepa's Blog
Auteur Henry Rzepa
tpap[cite]10.1055%2Fs-1994-25538[/cite], as it is affectionately known, is a ruthenium-based oxidant of primary alcohols to aldehydes discovered by Griffith and Ley.
References
Organic Chemistry
Anglais
Autocatalysis during the reduction of tetra-n-propylammonium perruthenate by 2-propanol
Publié in The Journal of Organic Chemistry
Auteurs Donald G. Lee, Zhao Wang, W. David Chandler
Anglais
Successful Computational Modeling of Isobornyl Chloride Ion-Pair Mechanisms
Publié in The Journal of Organic Chemistry
Auteurs Jing Kong, Paul v. R. Schleyer, Henry S. Rzepa
Organic ChemistryCatalysis
Anglais
Tetrapropylammonium Perruthenate, Pr4N+RuO4 -, TPAP: A Catalytic Oxidant for Organic Synthesis
Publié in Synthesis
Auteurs Steven V. Ley, Joanne Norman, William P. Griffith, Stephen P. Marsden
Organic ChemistryGeneral ChemistryCatalysis
Anglais
The oxidation of cyclobutanol by ruthenium tetroxide and sodium ruthenate
Publié in Canadian Journal of Chemistry
Auteurs Donald G. Lee, Udo A. Spitzer, James Cleland, Merle E. Olson
The only detectable product obtained from the oxidation of cyclobutanol by ruthenium tetroxide or sodium ruthenate is cyclobutanone. This indicates that both of these reagents act as two-electron transfer oxidants and that the oxidation of alcohols by ruthenium tetroxide likely proceeds via a mechanism that involves a pair of successive two-electron transfer steps.