Messages de Rogue Scholar

language
Publié in Henry Rzepa's Blog

My colleague Bill Griffith has again come up with another colour challenge: that of the ancient semi-precious stone Lapis Lazuli , mined in the mountains of Afghanistan for more than 6000 years and used by painters in some medieval paintings of the Virgin, the Wilton diptych etc.

Publié in Henry Rzepa's Blog

Some molecules, when you first see them, just intrigue. So it was with carbobenzene, the synthesis of a derivative of which was recently achieved by Remi Chauvin and co-workers (DOI: 10.1002/chem.200601193). Two additional carbon atoms have been inserted into each of the six C-C bonds in benzene. Carbobenzene The structure shows two resonance forms, which remind one of Kekulé and of course benzene itself.