Pubblicato in Henry Rzepa's Blog
Autore Henry Rzepa
tpap[cite]10.1055%2Fs-1994-25538[/cite], as it is affectionately known, is a ruthenium-based oxidant of primary alcohols to aldehydes discovered by Griffith and Ley.
References
Organic Chemistry
Inglese
Autocatalysis during the reduction of tetra-n-propylammonium perruthenate by 2-propanol
Pubblicato in The Journal of Organic Chemistry
Autori Donald G. Lee, Zhao Wang, W. David Chandler
Inglese
Successful Computational Modeling of Isobornyl Chloride Ion-Pair Mechanisms
Pubblicato in The Journal of Organic Chemistry
Autori Jing Kong, Paul v. R. Schleyer, Henry S. Rzepa
Organic ChemistryCatalysis
Inglese
Tetrapropylammonium Perruthenate, Pr4N+RuO4 -, TPAP: A Catalytic Oxidant for Organic Synthesis
Pubblicato in Synthesis
Autori Steven V. Ley, Joanne Norman, William P. Griffith, Stephen P. Marsden
Organic ChemistryGeneral ChemistryCatalysis
Inglese
The oxidation of cyclobutanol by ruthenium tetroxide and sodium ruthenate
Pubblicato in Canadian Journal of Chemistry
Autori Donald G. Lee, Udo A. Spitzer, James Cleland, Merle E. Olson
The only detectable product obtained from the oxidation of cyclobutanol by ruthenium tetroxide or sodium ruthenate is cyclobutanone. This indicates that both of these reagents act as two-electron transfer oxidants and that the oxidation of alcohols by ruthenium tetroxide likely proceeds via a mechanism that involves a pair of successive two-electron transfer steps.