Pubblicato in Henry Rzepa's Blog
Autore Henry Rzepa
A game chemists often play is to guess the mechanism for any given reaction. I thought I would give it a go for the decomposition of the tris-peroxide shown below.
References
Colloid and Surface ChemistryBiochemistryGeneral ChemistryCatalysis
Inglese
Decomposition of Triacetone Triperoxide Is an Entropic Explosion
Pubblicato in Journal of the American Chemical Society
Autori Faina Dubnikova, Ronnie Kosloff, Joseph Almog, Yehuda Zeiri, Roland Boese, Harel Itzhaky, Aaron Alt, Ehud Keinan