Messaggi di Rogue Scholar

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Pubblicato in Henry Rzepa's Blog

Whilst clusters of carbon atoms are well-known, my eye was caught by a recent article describing the detection of a cluster of boron atoms, B 40 to be specific.[cite]10.1038/nchem.1999[/cite] My interest was in how the σ and π-electrons were partitioned. In a C 40 , one can reliably predict that each carbon would contribute precisely one π-electron. But boron, being more electropositive, does not always play like that.

Pubblicato in Henry Rzepa's Blog

For those of us who were around in 1985, an important chemical IT innovation occurred. We could acquire a computer which could be used to draw chemical structures in one application, and via a mysterious and mostly invisible entity called the clipboard , paste it into a word processor (it was called a Macintosh). Perchance even print the result on a laserprinter.