Veröffentlicht in Henry Rzepa's Blog

The previous post explored why E2 elimination reactions occur with an antiperiplanar geometry for the transition state. Here I have tweaked the initial reactant to make the overall reaction exothermic rather than endothermic as it was before. The change is startling. The exothermicity is of course due to the aromatisation of the ring. The IRC is however quite different from before. IRC for E2 elimination.