Veröffentlicht in Henry Rzepa's Blog
Autor Henry Rzepa
tpap[cite]10.1055%2Fs-1994-25538[/cite], as it is affectionately known, is a ruthenium-based oxidant of primary alcohols to aldehydes discovered by Griffith and Ley.
References
Organic Chemistry
Englisch
Autocatalysis during the reduction of tetra-n-propylammonium perruthenate by 2-propanol
Veröffentlicht in The Journal of Organic Chemistry
Autoren Donald G. Lee, Zhao Wang, W. David Chandler
Englisch
Successful Computational Modeling of Isobornyl Chloride Ion-Pair Mechanisms
Veröffentlicht in The Journal of Organic Chemistry
Autoren Jing Kong, Paul v. R. Schleyer, Henry S. Rzepa
Organic ChemistryCatalysis
Englisch
Tetrapropylammonium Perruthenate, Pr4N+RuO4 -, TPAP: A Catalytic Oxidant for Organic Synthesis
Veröffentlicht in Synthesis
Autoren Steven V. Ley, Joanne Norman, William P. Griffith, Stephen P. Marsden
Organic ChemistryGeneral ChemistryCatalysis
Englisch
The oxidation of cyclobutanol by ruthenium tetroxide and sodium ruthenate
Veröffentlicht in Canadian Journal of Chemistry
Autoren Donald G. Lee, Udo A. Spitzer, James Cleland, Merle E. Olson
The only detectable product obtained from the oxidation of cyclobutanol by ruthenium tetroxide or sodium ruthenate is cyclobutanone. This indicates that both of these reagents act as two-electron transfer oxidants and that the oxidation of alcohols by ruthenium tetroxide likely proceeds via a mechanism that involves a pair of successive two-electron transfer steps.