Interesting ChemistryDouble BondHigh EnergyHistoricalQuadruple BondChemieEnglisch

A (very) short history of shared-electron bonds.

https://doi.org/10.59350/rj4gk-7jm52
Veröffentlicht in Henry Rzepa's Blog

The concept of a shared electron bond and its property of an order is almost 100 years old in modern form, when G. N. Lewis suggested a model for single and double bonds that involved sharing either 2 or 4 electrons between a pair of atoms[cite]10.1021/ja02261a002[/cite]. We tend to think of such (even electron) bonds in terms of their formal bond order (an integer), recognising that the actual bond order (however defined) may not fulfil this

References

Multidisciplinary
Englisch

Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers

https://doi.org/10.1126/science.1116789
Veröffentlicht in Science
Autoren Tailuan Nguyen, Andrew D. Sutton, Marcin Brynda, James C. Fettinger, Gary J. Long, Philip P. Power

Although in principle transition metals can form bonds with six shared electron pairs, only quadruply bonded compounds can be isolated as stable species at room temperature. Here we show that the reduction of {Cr(μ-Cl)Ar′} 2 [where Ar′ indicates C 6 H 3 -2,6(C 6 H 3 -2,6-Pr i 2 ) 2 and Pr indicates isopropyl] with a slight excess of potassium graphite has produced a stable compound with fivefold chromium-chromium (Cr–Cr) bonding. The very air- and moisture-sensitive dark red crystals of Ar′CrCrAr′ were isolated with greater than 40% yield. X-ray diffraction revealed a Cr–Cr bond length of 1.8351(4) angstroms (where the number in parentheses indicates the standard deviation) and a planar transbent core geometry. These data, the structure's temperature-independent paramagnetism, and computational studies support the sharing of five electron pairs in five bonding molecular orbitals between two 3d 5 chromium(I) ions.